Good podcasts that are Monero or at least Monero-related are... Monero Talk (of course), Monero Magazine, AlexAnarcho, Outlaw Crypto Podcast, Mental Outlaw, and Doinfedtime are a few
https://www.youtube.com/@MoneroTalk/videos
https://www.youtube.com/@moneromagazine/videos
https://alexanarcho.live/podcast/cypher-7
https://www.youtube.com/watch?v=pqN3RpopZQ0
https://www.youtube.com/watch?v=ZH5swpq-dN8